Dinuclear Phenoxo-Bridged Nickel(II) Complexes of Macrocyclic Ligands with Cyano Groups Laterally Introduced on a Conjugated System within the Ligands
作者:
Makoto Handa,
Akhter Farida,
LaurenceK. Thompson,
Chie Hayashibara,
Tamotsu Sugimori,
Ichiro Hiromitsu,
Kuninobu Kasuga,
期刊:
Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals
(Taylor Available online 2000)
卷期:
Volume 342,
issue 1
页码: 75-80
ISSN:1058-725X
年代: 2000
DOI:10.1080/10587250008038247
出版商: Taylor & Francis Group
关键词: dinuclear nickel(II) complex;macrocyclic ligand;π-conjugated system;cyano groups
数据来源: Taylor
摘要:
Diphenoxo-bridged dinuclear nickel(II) complexes of macrocyclic ligands having two cyano groups laterally introduced on a π-conjugated system within the ligands have been prepared and characterized. The reaction solvent DMF is coordinated to the nickel(II) ions to cause them high spin state. The antiferromagnetic interaction (J= ca. -10 cm−1) was observed between the nickel(II) ions.
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