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Dinuclear Phenoxo-Bridged Nickel(II) Complexes of Macrocyclic Ligands with Cyano Groups Laterally Introduced on a Conjugated System within the Ligands

 

作者: Makoto Handa,   Akhter Farida,   LaurenceK. Thompson,   Chie Hayashibara,   Tamotsu Sugimori,   Ichiro Hiromitsu,   Kuninobu Kasuga,  

 

期刊: Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals  (Taylor Available online 2000)
卷期: Volume 342, issue 1  

页码: 75-80

 

ISSN:1058-725X

 

年代: 2000

 

DOI:10.1080/10587250008038247

 

出版商: Taylor & Francis Group

 

关键词: dinuclear nickel(II) complex;macrocyclic ligand;π-conjugated system;cyano groups

 

数据来源: Taylor

 

摘要:

Diphenoxo-bridged dinuclear nickel(II) complexes of macrocyclic ligands having two cyano groups laterally introduced on a π-conjugated system within the ligands have been prepared and characterized. The reaction solvent DMF is coordinated to the nickel(II) ions to cause them high spin state. The antiferromagnetic interaction (J= ca. -10 cm−1) was observed between the nickel(II) ions.

 

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