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Interpretation of the Rheopexy by a Two‐Process Kinetic Model

 

作者: Yoichi Mikami,   Toshiro Masuda,   Shigeharu Onogi,  

 

期刊: Journal of Rheology  (AIP Available online 1982)
卷期: Volume 26, issue 3  

页码: 263-276

 

ISSN:0148-6055

 

年代: 1982

 

DOI:10.1122/1.549667

 

出版商: The Society of Rheology

 

数据来源: AIP

 

摘要:

A new kinetic theory has been proposed in which the formation of structure is assumed to take place in two processes. Combining structural parameters of the model with the viscosity, the variation of shearing stress with time for rheopectic suspensions has been described. A good agreement was obtained between theoretical predictions and experimental results obtained for suspensions of titanate fibers in a polymer solution. Rate constants for both the formation and breaking of network structure were evaluated as functions of rate of shear. The theory was also applied to a suspension of polystyrene particles investigated by Gadala‐Maria and Acrivos to evaluate rate constants. The dependence of the rate constants on rate of shear was found to be different from that for suspensions of titanate fibers.

 

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