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Synthesis of (±)-Epiderstatin

 

作者: Makoto Ubukata,   Tadamichi Sonoda,   Kiyoshi Isono,  

 

期刊: Natural Product Letters  （Taylor Available online 1992）
卷期: Volume 1, issue 2  

页码: 149-154

 

ISSN:1057-5634

 

年代: 1992

 

DOI:10.1080/10575639208048903

 

出版商: Taylor & Francis Group

 

关键词: Epiderstatin;glutarimide antibiotic;Swern oxidation;nitrile aldehyde;intramolecular amidoselenation

 

数据来源: Taylor

 

摘要:

A new glutarimide antibiotic epiderstatin was synthesized in dl-form. Horner-Wadsworth-Emmons reaction of an aldehyde with a phosphonate gave enones which were converted into (±)-epiderstatin and its diastereomerviaintramolecular amidoselenation as a key step.

 

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