Syntheses and Physical Properties of Ferrocene Derivatives (IX): Crystal Structure of a Ferrocene Derivative, ω-[4-(4-methoxyphenoxycarbonyl)phenoxy carbonyl]propyl 4-ferrocenylbenzoate
作者:
Naotake Nakamura,
Shigetaka Setodoi,
期刊:
Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals
(Taylor Available online 1998)
卷期:
Volume 312,
issue 1
页码: 253-261
ISSN:1058-725X
年代: 1998
DOI:10.1080/10587259808042445
出版商: Taylor & Francis Group
关键词: Crystal structure;X-ray diffraction;ferrocene derivative;metallomesogen;liquid crystal
数据来源: Taylor
摘要:
The structure of a mono-substituted ferrocene derivative of which the flexible spacer is located between the ferrocenyl and mesogenic groups, ω-[4-(4-methoxyphenoxycarbonyl)phenoxycarbonyl]propyl 4-ferrocenylbenzoate was determined by the X-ray diffraction method. It was found that the two cyclopentadienyl rings in the ferrocene and the—C3H6—chain introduced as a flexible spacer exhibited a very interesting conformation. The two cyclopentadienyl rings are a staggered conformation rather than an eclipsed one. This staggered conformation is an unusual structure in mono-substituted ferrocene derivatives, in general. Also, the—C3H6—chain includes twogaucheconformations and makes a bent molecular feature rather than a rod-like one. As a result, the title compound does not exhibit liquid crystallinity.
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