Monte carlo study of star‐branched polymers on the tetrahedral lattice. II. Statistical thermodynamics of single macromolecules
作者:
Andrzej Sikorski,
Andrzej Koliński,
期刊:
Journal of Polymer Science: Polymer Chemistry Edition
(WILEY Available online 1984)
卷期:
Volume 22,
issue 1
页码: 97-106
ISSN:0360-6376
年代: 1984
DOI:10.1002/pol.1984.170220110
出版商: John Wiley&Sons, Inc.
数据来源: WILEY
摘要:
AbstractThe thermodynamical properties of the star‐branched polymers on the tetrahedral lattice are studied taking into account nearest‐neighbor interactions. The excess free energy and energy and heat capacities are computed for wide ranges of chain lengths, reduced potential ϵ/kT, and number of branches. A significant influence of the degree of branching on long‐range interactions in the polymer random coil is observed. The possibilities of phase transitions in both linear and branched systems are discussed on the basis of the Monte Carl
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