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Monte carlo study of star‐branched polymers on the tetrahedral lattice. II. Statistical thermodynamics of single macromolecules

 

作者: Andrzej Sikorski,   Andrzej Koliński,  

 

期刊: Journal of Polymer Science: Polymer Chemistry Edition  (WILEY Available online 1984)
卷期: Volume 22, issue 1  

页码: 97-106

 

ISSN:0360-6376

 

年代: 1984

 

DOI:10.1002/pol.1984.170220110

 

出版商: John Wiley&Sons, Inc.

 

数据来源: WILEY

 

摘要:

AbstractThe thermodynamical properties of the star‐branched polymers on the tetrahedral lattice are studied taking into account nearest‐neighbor interactions. The excess free energy and energy and heat capacities are computed for wide ranges of chain lengths, reduced potential ϵ/kT, and number of branches. A significant influence of the degree of branching on long‐range interactions in the polymer random coil is observed. The possibilities of phase transitions in both linear and branched systems are discussed on the basis of the Monte Carl

 

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