Solid Surface Room Temperature Phosphorescence of Polychlorinated Dibenzofurans Enhanced by a Surface Active Agent
作者:
J.J. Santana Rodríguez,
J. Hernádez García,
Z. Sosa Ferrera,
A. J. Bermejo Martín Lázaro,
期刊:
Analytical Letters
(Taylor Available online 1995)
卷期:
Volume 28,
issue 13
页码: 2413-2436
ISSN:0003-2719
年代: 1995
DOI:10.1080/00032719508000382
出版商: Taylor & Francis Group
关键词: Room Temperature Phosphorescence;Dibenzofuran;Polychlorinated Dibenzofurans;Heavy Atom;Surfactant
数据来源: Taylor
摘要:
Room temperature phosphorescence characteristics on filter paper of dibenzofuran (DF) and several polychlorinated dibenzofurans (PCDFs) in the presence of different heavy atoms in conjunction with a surface active agent, sodium lauryl sulfate (NaLS), have been studied. The use of this surfactant produces an enhancement of the phosphorescence intensity in all the cases studied, which improve the sensitivity in the determination of DF and PCDFs. The optimization of experimental conditions like type of filter paper, drying and cooling times of the filter paper after spotting the sample, irradiation time, concentration of heavy atom and concentration of surfactant has been carried out. Phosphorescence lifetimes, linear dynamic range, relative standard deviation and limit of detection of the different compounds were also determined.
点击下载:
PDF (620KB)
返 回