Polymers containing stable free radicals, 4. Preparation of 2,4‐diphenyl‐6‐(3‐maleoyliminophenyl)‐3,4‐dihydro‐s‐tetrazin‐1(2H)‐yl and its anionic polymerization
作者:
Yozo Miura,
Masayoshi Kinoshita,
期刊:
Die Makromolekulare Chemie
(WILEY Available online 1974)
卷期:
Volume 175,
issue 1
页码: 23-29
ISSN:0025-116X
年代: 1974
DOI:10.1002/macp.1974.021750104
出版商: Hüthig&Wepf Verlag
数据来源: WILEY
摘要:
Abstract2,4‐Diphenyl‐6‐(3‐maleoyliminophenyl)‐3,4‐dihydro‐s‐tetrazin‐1(2H)‐yl (6) was synthesized and anionically polymerized with a catalytic amount of sodium 1,4‐dihydro‐1,4‐naphthalenediide, with a conversion up to 96%. The polymer was a dark green powder with a content of radical groups of about 58% (based on unit mol), and its relative molecular mass was about 4 800, correspond
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