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Observation of disclinations in the nematic state of a thermotropic aromatic copolyester by lamellar decoration

 

作者: Shouxi Chen,   Liying Cai,   Yongzheng Wu,   Yongze Jin,   Shufan Zhang,   Zhihai Qin,   Wenhui Song,   Renyuan Qian,  

 

期刊: Liquid Crystals  (Taylor Available online 1993)
卷期: Volume 13, issue 3  

页码: 365-371

 

ISSN:0267-8292

 

年代: 1993

 

DOI:10.1080/02678299308026310

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

The frozen nematic state of a thermotropic aromatic copolyester exhibits a schlieren texture with two and four dark brushes emanating from a point observed under a polarizing optical microscope; these correspond to disclination strengthss= ± ½ ands= ± 1, respectively. The combined techniques of lamellar decoration and ruthenium tetraoxide staining have been used to reveal the director orientation around disclinations in the frozen nematic state of polymers by transmission electron microscopy. All six disclinations in the nematic mesophase of a single liquid-crystalline aromatic copolyester have been observed. Every disclination interacts and is connected with its neighbouring disclination so that disclination exist in pairs usually of opposite sign in their disclination strengths. Some pairs with the same sign disclination have also been observed.

 

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