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A Critical Review of H‐Atom Transfer in the Liquid Phase: Chlorine Atom, Alkyl, ...
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A Critical Review of H‐Atom Transfer in the Liquid Phase: Chlorine Atom, Alkyl, Trichloromethyl, Alkoxy, and Alkylperoxy Radicals
作者:
D. G. Hendry,
T. Mill,
L. Piszkiewicz,
J. A. Howard,
H. K. Eigenmann,
期刊:
Journal of Physical & Chemical Reference Data
(AIP Available online 1974)
卷期:
Volume 3,
issue 4
页码: 937-978
ISSN:0047-2689
年代: 1974
DOI:10.1063/1.3253151
出版商: AIP
数据来源: AIP
摘要:
This review covers hydrogen‐atom transfer from carbon‐hydrogen bonds in organic compounds to chlorine atom, methyl, ethyl, trichloromethyl, t‐butoxy and alkylperoxy radicals in the liquid phase. Rate constant data are presented in 38 tables. Literature is covered through most of 1972. The review is divided into six sections; an introduction plus five sections each dealing with specific radicals. Hydrogen‐atom transfer to chlorine atom are presented as relative rate constants. For hydrogen‐atom transfer to methyl, ethyl, trichloromethyl, and t‐butoxy radicals, both relative and absolute rate constants are tabulated. For alkylperoxy radicals only absolute rate constants are listed. Each absolute rate constant has a tabulated set of rate parameters whereAhas been assigned andEderived from the Arrhenius equation.
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