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Controlled Composition in Emulsion Copolymerization Application to Butadiene-Acrylonitrile Copolymers

 

作者: A. Guyot,   J. Guillot,   C. Graillat,   M.F. Llauro,  

 

期刊: Journal of Macromolecular Science: Part A - Chemistry  (Taylor Available online 1984)
卷期: Volume 21, issue 6-7  

页码: 683-699

 

ISSN:0022-233X

 

年代: 1984

 

DOI:10.1080/00222338408077233

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

The use of gas chromatographic analysis of the actual monomer mixture at fixed time intervals to monitor the composition of copolymers in emulsion copolymerization has been described previously. The design has been now improved by the insertion of a dilution cell to avoid flocculation problems in the loop carrying the reaction medium from the reactor to the injection kit of the chromatograph. Then the copolymerization can be monitored up to completion. This system has been applied to the copolymerization of butadiene and acrylonitrile, and constant composition runs have been compared to the batch. Two main differences are observed. (1) Constant composition copolymers show a unique glass transition interval of limited width instead of two or at least one broad temperature interval for the copolymer produced in batch. (2) In the monitored copolymerizations, the production of insoluble gels is delayed and sometimes totally avoided. The production of the gels is related to the formation of 1,2-butadiene units which appear to be preferentially present in long sequences of butadiene units. The cross-linking process involves the consumption of the pendent vinyl groups by copolymerization with the monomers.

 

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