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Transient enhanced diffusion from decaborane molecular ion implantation

 

作者: Aditya Agarwal,   H.-J. Gossmann,   D. C. Jacobson,   D. J. Eaglesham,   M. Sosnowski,   J. M. Poate,   I. Yamada,   J. Matsuo,   T. E. Haynes,  

 

期刊: Applied Physics Letters  (AIP Available online 1998)
卷期: Volume 73, issue 14  

页码: 2015-2017

 

ISSN:0003-6951

 

年代: 1998

 

DOI:10.1063/1.122353

 

出版商: AIP

 

数据来源: AIP

 

摘要:

Transient enhanced diffusion (TED) from implantation of5 keV B10H14and 0.5 keV B ions has been quantified and compared for nominal boron doses of1014and1015 cm−2.Boron diffusivity during annealing was extracted from secondary ion mass spectroscopy depth profiles of diffused marker layers in boron doping-superlattices and the actual implanted B dose was independently measured by nuclear reaction analysis. Comparable enhancements were observed from both ions. Transmission electron microscopy analysis revealed that both boron- and decaborane-implanted samples were amorphized at a nominal1015 cm−2 Bdose. A comparison with data from low energy Si implants revealed a similar dependence of diffusivity enhancement on implant dose. These findings are consistent with the understanding that TED is caused by the interstitial supersaturation resulting from a number of excess interstitials approximately equal to the number of implanted atoms which can become substitutional in the silicon lattice. Accordingly, no contribution to TED is expected from the hydrogen in theB10H14ions and none is observed. Furthermore, there is no detectable effect in the diffusion profiles which can be attributed to a difference in the ion damage produced by the decaborane molecule and the boron atom. In both cases the reduction in diffusivity enhancement is due only to proximity of the implantation-induced excess interstitials to the wafer surface. ©1998 American Institute of Physics.

 

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