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Silicon epitaxy by low-energy plasma enhanced chemical vapor deposition

 

作者: C. Rosenblad,   H. R. Deller,   A. Dommann,   T. Meyer,   P. Schroeter,   H. von Känel,  

 

期刊: Journal of Vacuum Science&Technology A: Vacuum, Surfaces, and Films  (AIP Available online 1998)
卷期: Volume 16, issue 5  

页码: 2785-2790

 

ISSN:0734-2101

 

年代: 1998

 

DOI:10.1116/1.581422

 

出版商: American Vacuum Society

 

关键词: Si

 

数据来源: AIP

 

摘要:

A new technique for semiconductor epitaxy at low substrate temperatures is presented, called low-energy dc plasma enhanced chemical vapor deposition. The method has been applied to Si homoepitaxy at substrate temperatures between 400 and 600 °C and growth rates between 0.1 and 1 nm/s, using silane as the reactive gas. The quality of the Si films has been examined by reflection high-energy electron diffraction, scanning tunneling microscopy, cross-section transmission electron microscopy, and high-resolution x-ray diffraction. Two effects have been identified to lead to the formation of stacking faults after an initial layer of defect-free growth: (1) substrate bombardment by ions with energies in excess of 15 eV, and (2) hydrogen adsorption limiting the surface mobility of Si atoms and silane radicals. Both result in the accumulation of surface roughness, facilitating the nucleation of stacking faults when the roughness reaches a critical level. Defect introduction can be eliminated effectively by biasing the substrate during growth and by decreasing the hydrogen coverage, either by admixing small amounts of germane to the silane or by using a sufficiently high plasma density.

 

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