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A New Versatile and Sensitive Monitoring System for Liquid Chromatography: Cerate Oxidation and Fluorescence Measurement

 

作者: S. Katz,   W.W. Pitt,  

 

期刊: Analytical Letters  (Taylor Available online 1972)
卷期: Volume 5, issue 3  

页码: 177-185

 

ISSN:0003-2719

 

年代: 1972

 

DOI:10.1080/00032717208066105

 

出版商: Taylor & Francis Group

 

关键词: Cerate Oxidation;Cerium (III) Fluorescence;Liquid Chromatography;Organic Acids;Reducing Compounds

 

数据来源: Taylor

 

摘要:

A new liquid chromatographic detector depends upon the fluorescence measurement of cerium (III) produced from the reaction of cerium (IV) with eluted reducible compounds. It is more sensitive than previous oxidative detectors by more than a factor of 100. The reaction can be varied to discriminate among compounds according to ease of oxidation.

 

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