首页   按字顺浏览 期刊浏览 卷期浏览 Structural Correlations in the Pyrolytic Degradation of Copolymers of Methyl Methacryla...
Structural Correlations in the Pyrolytic Degradation of Copolymers of Methyl Methacrylate and Purem- andp-Divinylbenzene

 

作者: RichardH. Wiley,   FrankE. Martin,  

 

期刊: Journal of Macromolecular Science: Part A - Chemistry  (Taylor Available online 1967)
卷期: Volume 1, issue 4  

页码: 635-642

 

ISSN:0022-233X

 

年代: 1967

 

DOI:10.1080/10601326708054000

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

The rates of formation of pyrolysis products, identified by gas-liquid chromatography, of copolymers of methyl methacrylate with purem- and with purep-divinylbenzene show that the products derived from the meta-disubstituted unit in the meta cross-linked copolymer appear more rapidly than do those from the para-disubstituted units. This confirms the similar observation with corresponding styrene copolymers. The data from the methacrylate copolymers provide a less complicated degradative pattern, since depolymerization is the principal degradative process. The analytical data are less complicated also. The basic assumption that the relative rates of appearance of the disubstituted fragments are related to the distribution of the divinyl derived units in the network is, therefore, strengthened.

 

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