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Efficient Photochemical Switching of Metal-Ion Complexation by Malachite Green Leuconitrile Derivatives Carrying Bis(crown ether)

 

作者: RyokoM. Uda,   Masaaki Yokoyama,   Keiichi Kimura,  

 

期刊: Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals  （Taylor Available online 2000）
卷期: Volume 344, issue 1  

页码: 133-138

 

ISSN:1058-725X

 

年代: 2000

 

DOI:10.1080/10587250008023826

 

出版商: Taylor & Francis Group

 

关键词: crown ether;Malachite Green;metal-ion complexation;photoionization;kinetics;MO calculation

 

数据来源: Taylor

 

摘要:

A Malachite Green derivative incorporating a bis(monoazacrown ether) structure enables efficient photocontrol of metal ion complexation. Its photochromism in the presence of alkali metal ions is examined by kinetics measurements and molecular-orbital (MO) calculation.

 

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