The Acid-Catalyzed Hydrolysis of Anomeric Alkyl Fructofuranosides
作者:
Harri Lönnberg,
Outi Gylén,
期刊:
Journal of Carbohydrate Chemistry
(Taylor Available online 1983)
卷期:
Volume 2,
issue 2
页码: 177-188
ISSN:0732-8303
年代: 1983
DOI:10.1080/07328308308057866
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The rate constants for the hydrolysis of some al-kyl α- and β-d-fructofuranosides in aqueous perchloric acid have been determined at various temperatures. The effects of varying the aglycon structure on the hydrolysis rate suggest, together with the markedly positive entropies of activation, that the substrate, protonated on the glycosidic oxygen atom, undergoes a rate-limiting unimolecular heterolysis to form a glycosyl oxocar-benium ion. The rate variations in mixtures of aqueous perchloric acid and dimethyl sulfoxide are interpreted as lending further support for the proposed mechanism.
点击下载:
PDF (374KB)
返 回