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Forced Oscillations in a Nonisothermal Continuous Polymerization Reactor

 

作者: D. Konopnicki,   J.L. Kuester,  

 

期刊: Journal of Macromolecular Science: Part A - Chemistry  (Taylor Available online 1974)
卷期: Volume 8, issue 5  

页码: 887-908

 

ISSN:0022-233X

 

年代: 1974

 

DOI:10.1080/00222337408066406

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

A dynamic model of a nonisothermal continuous stirred tank polymerization reactor is developed to predict product molecular weight distribution parameters. Deliberate oscillations in operating variables were programmed into the model and the resulting time-averaged reactor performance indices compared with that for optimum steady-state operation. Results indicate that periodic operation does influence polymerization reactor performance, particularly with regard to time-averaged molecular weight polydispersity. Significant resonant behavior was encountered with molecular weight properties at low frequencies.

 

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