Stoichiometric salt‐linkage formation of trimethylammonium glycol chitosan iodide with a carboxylic type ion exchanger
作者:
Etsuo Kokufuta,
Susumu Fujii,
Isei Nakamura,
期刊:
Die Makromolekulare Chemie
(WILEY Available online 1982)
卷期:
Volume 183,
issue 5
页码: 1233-1238
ISSN:0025-116X
年代: 1982
DOI:10.1002/macp.1982.021830517
出版商: Hüthig&Wepf Verlag
数据来源: WILEY
摘要:
AbstractThe adsorption of trimethylammonium glycol chitosan iodide (TGCI) on Dowex CCR‐2 resin was investigated at different pH values and resin weights. The concentration of Na+or Ca2+ions, released by the ion exchange reaction with TGCI, was measured by inductively coupled plasma spectroscopy. It was found that the amount of the released ions is comparable to that of the absorbed TGCI. This indicates that the salt‐linkage formation of carboxylate ions of the exchanger with ⊕N(CH3)3‐groups in TGCI follows a stoichiometric relationship. This result is discussed in connection with the form of the polymer layer adsorbed on the solid
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