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Vinylogous Nucleophilic Substitution: A Route to New Polymers

 

作者: J.A. Moore,   T.D. Mitchell,  

 

期刊: Journal of Macromolecular Science: Part A - Chemistry  （Taylor Available online 1985）
卷期: Volume 22, issue 5-7  

页码: 755-764

 

ISSN:0022-233X

 

年代: 1985

 

DOI:10.1080/00222338508056634

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

The basic chemistry underlying the successful synthesis of poly-(enaminoesters) by vinylogous nucleophilic substitution is examined. It is concluded that a new mechanism must be operative. A Michael addition followed by elimination of a volatile fragment is proposed.

 

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