Infrared emission studies of the vibrational deactivation of benzene derivatives
作者:
JohnR. Barker,
BeatrizM. Toselli,
期刊:
International Reviews in Physical Chemistry
(Taylor Available online 1993)
卷期:
Volume 12,
issue 2
页码: 305-338
ISSN:0144-235X
年代: 1993
DOI:10.1080/01442359309353284
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
This paper reviews the time-resolved infrared fluorescence technique and its application to studies of the deactivation of highly vibrationally excited benzene-d0, benzene-d6, toluene-d0, and toluene-d8. The energy transfer parameters obtained are summarized in terms of both «ΔE» and <ΔE>d, the average total energy transferred per collision and the average energy transferred in deactivating collisions, respectively. The mechanisms of energy transfer have also been investigated to determine the roles of vibration-to-translation/rotation and vibration-to-vibration energy transfer and the possible influence of quantum effects. The review concludes with a brief summary of a current view of large molecule energy transfer and suggestions for future work.
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