A new series of laterally linked novel twin mesogenic compounds were synthesized and their liquid crystalline properties studied by differential scanning calorimetry, polarizing microscopy and X-ray analysis. The compounds, 1,6-bis[(2,5-bis(4-alkoxy)phenoxycarbonyl)phenoxy]hexanes, consisted of two identical mesogenic structures of bis(alkoxyphenoxy)terephthalate linked laterally on the terephthalate centre through a 1,6-dioxyhexane spacer. The length of the terminal alkoxy groups was varied from the ethoxy to the heptyloxy group; the dodecyloxy group was also included in the present study. It was found that the compounds carrying the ethoxy to hexyloxy groups are monotropically nematic whereas that carrying the heptyloxy groups is enantiotropically nematic. Only the compound with the longest dodecyloxy terminals forms the smectic A phase enantiotropically.