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Crystal and molecular structure of 1-(trimethylsilylmethyl)hexahydroazepine-2-thione and hexahydroazepine-2-thione

 

作者: A.O.Mozzhukhin,   Yu.E.Ovchinnikov,   M.Yu.Antipin,   Yu.T.Struchkov,   A.G.Shipov,   V.N.Sergeev,   S.A.Artamkin,   Yu.I.Baukov,  

 

期刊: Russian Chemical Bulletin  （Springer Available online 2004）
卷期: Volume 42, issue 1  

页码: 181-184

 

ISSN:1066-5285

 

年代: 2004

 

DOI:10.1007/BF00700005

 

出版商: Springer_US-Boston

 

数据来源: Springer

 

摘要:

The title compounds were prepared and X-ray analysis was performed (R = 0.064 and 0.035 for 1309 and 1637 reflections, respectively). In the former the intramolecular S→Si coordination interactions are absent and the Si atom has undistorted tetrahedral coordination with an S...Si distance of 4.034 Å. Crystals of the latter are built of centrosymmetric dimeric H-complexes (S...H(N) 2.58 Å, the S...HN angle 16

 

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