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Polar and quadrupolar order in smectic liquid crystals

 

作者: P. SCHILLER,   H. SCHLACKEN,  

 

期刊: Liquid Crystals  (Taylor Available online 1998)
卷期: Volume 24, issue 4  

页码: 619-626

 

ISSN:0267-8292

 

年代: 1998

 

DOI:10.1080/026782998207109

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

In several smectic phases the long molecules are tilted towards the layer planes. The molecules in the layers of smectic C phases have a preferred tilt direction with a C2 rotation axis perpendicular to the tilt plane. If the molecules have a brick-like shape, a configuration possessing the D2h symmetry is also possible. For molecules shaped like chevrons or bananas, the existence of a smectic phase with the symmetry Cv was recently reported. We consider different in-plane configurations of smectics using a geometrical approach based on the 'scaled particle theory'. Varying the geometrical parameters of hard rod particles, a phase diagram for several smectic configurations is predicted. Depending on the particle shape, phases with dipolar order (C2,Cv) and quadrupolar order (D2h) can be stable.

 

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