Berechnung der molekularen Hauptpolarisierbarkeiten von einigen 4, 4′-Di-n-alkoxy-azobenzolen und einigen 4, 4′-Di-n-alkoxyazoxybenzolen aus den Hauptdielektrizitätskonstanten der nematischen Schichten
作者:
A. Axmann,
期刊:
Molecular Crystals
(Taylor Available online 1968)
卷期:
Volume 3,
issue 4
页码: 471-478
ISSN:0369-1152
年代: 1968
DOI:10.1080/15421406808082892
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The principal molecular polarizabilities of some molecules of the 4, 4′-di-n-alkyloxy-azobenzenes and of the 4, 4′-di-n-alkyloxy-azoxy-benzenes are calculated of the high frequency dielectric constants ϵ1∞and ϵ2∞of the magnetically oriented nematic liquid crystals. The increases of the principal polarizabilities of such molecules in complete trans-forms by adding CH2groups to the alkyl chains are known from an estimation. By comparing these values to the differences between the principal polarizabilities of the investigated molecules it follows that the molecules in the liquid crystals are in a stretched form.
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