Nucleophilic Substitutions to Carbonic Acid Derivates. XII. Kinetics and Mechanism of the Reaction of N‐Nitro‐N‐alkyl‐urethanes with Primary Aliphatic AminesThe aminolysis of N‐alkyl‐N‐nitrourethanes takes place, as the kinetical studies demonstrate, by means of several consecutive steps.The nucleophilic attack of the amine (first step; reaction B), as well as the proton‐transfere (second step; reaction C), are quick pre‐equilibres, followed by the slow, rate‐determining elimination of the nitramino‐group (reaction D).During the deprotonation, an intermediate with two to the nitramino‐group antiperiplanar orbitals is formed, providing the necessary mesomeric assist