The Reactions of Sulfilimines withTCNQ and their Characteristic Charge-Transfer Complexes as Products
作者:
Shun-Ichi Mitomo,
Shinji Tsuchiya,
Manabu Senā,
Sumio Tokita,
期刊:
Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals
(Taylor Available online 1998)
卷期:
Volume 312,
issue 1
页码: 263-283
ISSN:1058-725X
年代: 1998
DOI:10.1080/10587259808042446
出版商: Taylor & Francis Group
关键词: Sulfilimine;TCNQ;charge-transfer complex
数据来源: Taylor
摘要:
The reactions of sulfilimines with TCNQ were undertaken to investigate the electronic structure of the sulfilimine. The reaction of ylide bond (S = N) of sulfilimine with the multiple bonds (C = C or C ≡ N of TCNQ does not occur, but new charge-transfer complexes were formed as products. The molar ratio of the sulfilimine and TCNQ in new charge-transfer complex I was 1:1.3. This ratio was determined by elemental analyses. The results of various thermal analyses indicated that these complexes do not have definite melting points. The reason for this result is that the sulfilimine is instabilized by the weakened ylide bond in the complex, because IR data showed that the electron transfer from ylide bond to TCNQ in the complex occurs and as a consequence, the bond strength of ylide bond is weakened. ESR measurements of various sulfilimine-TCNQ complexes were performed. It was also clarified from the measurements of conductivities that the behaviors of conductivity of new complexes are similar to those of typical charge-transfer complexes.
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