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Molecular motions in a smectic A phase by incoherent quasielastic neutron scattering

 

作者: A.J. Leadbetter,   R.M. Richardson,  

 

期刊: Molecular Physics  (Taylor Available online 1978)
卷期: Volume 35, issue 4  

页码: 1191-1200

 

ISSN:0026-8976

 

年代: 1978

 

DOI:10.1080/00268977800100871

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

Results are presented of incoherent quasi-elastic neutron-scattering measurements in ethyl 4-(4′acetoxybenzylidene) aminocinnamate (EABAC) in crystal,SAand nematic phases. Discussion is concentrated on data for theSAphase of an aligned, tail deuteriated, sample forQ⊥nandQ‖n, whereQis the scattering vector andnthe direction of the unique axis (the layer normal). The scattering lawS(Q, ω) is found to be essentially identical for the two directions. Analysis of the results shows that the molecules undergo rapid reorientation about the long axes withDr∼3×1010rad s-1, together with a random but bound motion predominantly normal to the layers with an r.m.s. amplitude <Z2>1/2∼1·2-1·8 Å, depending on the model, and a correlation time ∼ 10-11s.

 

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