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Thermoelastic Expansion and Creep of Polyethylene Terephthalate and Polypyromelitimide Film and Polyethylene Terephthalate Fibers from 20 to 295 K

 

作者: P. M. McConnell,   D. E. Daney,   J. B. Kirgis,  

 

期刊: Journal of Applied Physics  (AIP Available online 1970)
卷期: Volume 41, issue 13  

页码: 5066-5070

 

ISSN:0021-8979

 

年代: 1970

 

DOI:10.1063/1.1658601

 

出版商: AIP

 

数据来源: AIP

 

摘要:

A quartz tube dilatometer was used to measure the lineal thermal expansion and creep of single lengths of polyethylene terephthalate (PETP) film, polypyromelitimide (PPMI) film, and PETP multifiber yarn, while stressed under constant tension. Tensions below and above the conventionally defined yield strength were used and the sample temperature ranged from 20 to 295 K. Relative creep strain measurements, taken at the constant temperatures 77, 195, and 295 K were found to obey the equation&egr;=exp[−2.3 exp(A′y)]whereyis a function of stress, time, and temperature andA′ is a constant depending on the material. This equation was used to correct the thermoelastic expansion measurements for creep at the higher stresses. PETP multifiber yarn subjected to a slight tension was found to elongate during cooldown from 293 to 20 K. Higher stresses caused less elongation; i.e., the coefficient of expansion increased with stress. This result is believed to be due to changes in crystallinity at the higher stresses. A similar stress effect was found with PETP film but not with PPMI film. The thermoelastic expansion of the film samples was also found to be sensitive to the thickness.

 

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