These notes summarize the lectures delivered in the V Mexican School of Particle Physics, at the University of Guanajuato. We give a survey of the application of Ashtekar’s variables to the quantization of General Relativity in four dimensions with special emphasis on the application of techniques of analytic knot theory to the loop representation. We discuss the role that the Jones Polynomial plays as a generator of nondegenerate quantum states of the gravitational field. © 1994American Institute of Physics