Room-temperature near-ultraviolet electroluminescence from a linear silicon chain
作者:
Chien-Hua Yuan,
Satoshi Hoshino,
Seiji Toyoda,
Hiroyuki Suzuki,
Michiya Fujiki,
Nobuo Matsumoto,
期刊:
Applied Physics Letters
(AIP Available online 1997)
卷期:
Volume 71,
issue 23
页码: 3326-3328
ISSN:0003-6951
年代: 1997
DOI:10.1063/1.120326
出版商: AIP
数据来源: AIP
摘要:
Single-layer light emitting diodes (LEDs) were fabricated using poly[bis(p-butylphenyl)silane] as the emissive layer. An efficient and stable electroluminescence with a maximum at 407 nm was observed at room temperature under a forward electric field greater than6×105 V/cm.The coincidence of electroluminescence with photoluminescence suggests the origin of the electroluminescence in an excited silicon chain segment. The high external quantum efficiency (0.1&percent; photons/electron), narrow emission (full width at halfmaximum=15 nm), improved operating stability, and good solubility in organic solvents provide the possibility of using polysilanes for ultraviolet LEDs. ©1997 American Institute of Physics.
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