The Diffusion of Divalent Europium into Single Crystals of Potassium Chloride
作者:
Renata Reisfeld,
A. Honigbaum,
期刊:
Israel Journal of Chemistry
(WILEY Available online 1968)
卷期:
Volume 6,
issue 1
页码: 53-59
ISSN:0021-2148
年代: 1968
DOI:10.1002/ijch.196800008
出版商: WILEY‐VCH Verlag
数据来源: WILEY
摘要:
AbstractThe diffusion of europium was studied in single crystals of potassium chloride by the spectrophotometric method. Measurements were carried out in the temperature range 418–550†C. The absorption spectra as well as the fluorescence spectra of crystals showed that europium diffused in its divalent state, being reduced by the crystal field of potassium chloride. The diffusion of europium can be represented by the equation D = 6.45. 10−2exp(‐29.400/RT). It is concluded that the activation energy consists of the sum of the jump energy of Eu2+and of the enthalpy of solution of EuCl
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