首页   按字顺浏览 期刊浏览 卷期浏览 Donor-Acceptor Complexes in Copolymerization. IX. Kinetic Features of Copolymerization ...
Donor-Acceptor Complexes in Copolymerization. IX. Kinetic Features of Copolymerization of Styrene and Methyl Methacrylate… Al(C2H5))1.5Cl1.5

 

作者: NormanC. Gaylord,   Bohumir Matyska,  

 

期刊: Journal of Macromolecular Science: Part A - Chemistry  (Taylor Available online 1970)
卷期: Volume 4, issue 7  

页码: 1519-1528

 

ISSN:0022-233X

 

年代: 1970

 

DOI:10.1080/00222337008069367

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

The kinetic features of the copolymerization of styrene and methyl methacrylate in the presence of ethylaluminum sesquichloride in toluene do not unequivocally distinguish between first- and second-order reactions. The reaction does not attain steady-state conditions. The course of the reaction is apparently influenced by many factors including the dissociation of the polymerizable complex into unreactive monomeric species and physical phenomena such as diffusion and dilution effects as well as matrix formation. The use of azobisisobutyronitrile as an initiator indicates apparent bimolecu-lar termination but the kinetic curves show deviation from linearity.

 

点击下载:  PDF (332KB)



返 回