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Crystallization of polycarbonate from the glassy state. part II. Thin films melted and quenched

 

作者: A. Siegmann,   P.H. Geil,  

 

期刊: Journal of Macromolecular Science, Part B  (Taylor Available online 1970)
卷期: Volume 4, issue 2  

页码: 273-291

 

ISSN:0022-2348

 

年代: 1970

 

DOI:10.1080/00222347008212503

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

The crystallization of glassy amorphous thin polycarbonate films quenched from the melt has been followed. Structures similar to those observed during the crystallization of films containing small amount of adsorbed solvent are formed. However, crystallization, at the same temperatures, is much slower and more irregular. Preannealing of the samples below Tgaffects the crystallization process, increasing the nucleation rate. Annealing above Tgdoes not destroy all order gained by annealing below Tg.

 

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