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Double Resonance Modulated Microwave Spectrometer

 

作者: R. C. Woods,   A. M. Ronn,   E. Bright Wilson,  

 

期刊: Review of Scientific Instruments  (AIP Available online 1966)
卷期: Volume 37, issue 7  

页码: 927-933

 

ISSN:0034-6748

 

年代: 1966

 

DOI:10.1063/1.1720367

 

出版商: AIP

 

数据来源: AIP

 

摘要:

A practical non‐Stark modulated double resonance microwave spectrometer has been constructed and tested in which frequency modulation is applied to one (strong) microwave source, the power from which passes through the sample gas but is prevented from reaching the crystal by filters. The second source does reach the crystal but is unmodulated. The modulation is therefore transmitted to the crystal and tuned amplifier exclusively via the phenomenon of double quantum absorption. The only transitions observed were those which occur as active pairs involving a common energy level, the two frequencies being near the two source frequencies. This provides extremely specific spectra for identification in complex situations, and is a convenient way of searching for linked transitions which are useful for assignment purposes. Because no Stark electrode is needed, it is easier to construct special absorption cells such as coiled guides, high temperature cells, free space paths, etc.

 

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