首页   按字顺浏览 期刊浏览 卷期浏览 Effects of molecular weight on the perforation impact behavior of injection-molded plaq...
Effects of molecular weight on the perforation impact behavior of injection-molded plaques of α-and β-phase isotactic polypropylenes

 

作者: J. Karger-kocsis,   E. Moos,   I. Mudra,   J. Varga,  

 

期刊: Journal of Macromolecular Science, Part B  (Taylor Available online 1999)
卷期: Volume 38, issue 5-6  

页码: 647-662

 

ISSN:0022-2348

 

年代: 1999

 

DOI:10.1080/00222349908248128

 

出版商: Taylor & Francis Group

 

关键词: α-phase;β-phase;Injection molding;Instrumented falling weight impact;Isotactic polypropylene;Molecular weight;Skin-core morphology.

 

数据来源: Taylor

 

摘要:

This study was devoted to the instrumented falling weight impact (IFWI) behavior of injection-molded a-and β-phase isotactic polypropylene (iPP) homopolymers. The perforation impact response of iPP with various melt flow indices (MFIs), and thus molecular weight (MW) characteristics, was studied at two different temperatures (T= 23°C andT=−40°C) and incident impact speeds (vinc= 5 and 10 m/s). The impact resistance of β-iPP was superior to the α-modification. The absolute resistance to perforation increased with increasing MW or decreasing MFI, whereas the relative toughness improvement between the β-and α-iPPs followed an opposite tendency. The molding-induced skin-core morphology did not affect practically the out-of-plane response of the impacted plaques. Changes in the fractograms (viz. force-time curves) under various experimental conditions were traced to variations in the failure mode, showing a competition between radial and circumferential cracking with respect to the clamping ring. In the case of the more ductile β-iPP. circumferential cracking was favored.

 

点击下载:  PDF (816KB)



返 回