Concerning free volume quantities and the glass temperature
作者:
Robert Simha,
CharlesE. Weil,
期刊:
Journal of Macromolecular Science, Part B
(Taylor Available online 1970)
卷期:
Volume 4,
issue 1
页码: 215-226
ISSN:0022-2348
年代: 1970
DOI:10.1080/00222347008212482
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Free volume quantities proposed earlier by Boyer and Simha in connection with the glass transition are reformulated by taking into account the temperature dependence of the thermal expansivities αland αgfor the liquid and the glass, respectively. This necessitates an extrapolation of the liquid to temperatures below Tg which is performed by means of the reduced volume-temperature function established and given a theoretical foundation previously. For the glass, low temperature experimental data, encompassing all relaxations occuring below Tg, are required.
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