The planar conformation of 2-methylthiobenzaldehyde in solution
作者:
Ted Schaefer,
Rudy Sebastian,
期刊:
Canadian Journal of Chemistry
(NRC Available online 1983)
卷期:
Volume 61,
issue 1
页码: 26-28
ISSN:0008-4042
年代: 1983
DOI:10.1139/v83-005
出版商: NRC Research Press
数据来源: NRC
摘要:
The1H nmr spectral parameters are extracted for a 4 mol% solution of 2-methylthiobenzaldehyde in CCl4at 305 K. The long-range spin–spin coupling constants involving the aldehydic and methyl protons are consistent only with a preferred conformation in which all heavy atoms are coplanar, as are the chemical shifts of the ring and methyl protons. This conclusion contradicts previous interpretations of the dipole moment, the nmr parameters, and of the infrared data for CCl4solutions. The present data show that theO-synandO-antiforms of the compound are present in roughly equal proportions.
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