Ionic Jump Distance and Glass Transition of Polyvinyl Chloride
作者:
Masamitsu Kosaki,
Koichi Sugiyama,
Masayuki Ieda,
期刊:
Journal of Applied Physics
(AIP Available online 1971)
卷期:
Volume 42,
issue 9
页码: 3388-3392
ISSN:0021-8979
年代: 1971
DOI:10.1063/1.1660742
出版商: AIP
数据来源: AIP
摘要:
The electrical conduction of polyvinyl chloride was measured from low electric field to high field near breakdown below, in, and above a glass transition region. Ionic conduction was found to hold up to the field near breakdown. The estimated jump distance of a charge carrier changes considerably in the glass transition region, while it remains constant (12 Å) at a temperature fairly below the glass transitionTg(=87°C) and seems to reach a saturation value (30 Å) aboveTg. The elongation of substantial jump distance may be explained by the change in the shape and height of potential barriers against ionic migration due to the liberation of micro‐Brownian motion of main chains in the glass transition region.
点击下载:
PDF
(368KB)
返 回