Criteria for bombardment-induced structural changes in non-metallic solids
作者:
H.M. Naguib,
Roger Kelly,
期刊:
Radiation Effects
(Taylor Available online 1975)
卷期:
Volume 25,
issue 1
页码: 1-12
ISSN:0033-7579
年代: 1975
DOI:10.1080/00337577508242047
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Structural transformations in non-metallic solids induced by energetic heavy ions at intermediate (∼1013−1016ions/cm2) and high (∼ 1017ions/cm2) doses normally take the form of amorphization, crystallization, or stoichiometry changes. Using the results of 72 substances both a temperature-ratio and a bond-type criterion are shown to be successful in predicting the occurrence of amorphization or crystallization. The former, based on a physical model involving thermal spikes, states that amorphization should occur whenever the ratio (crystallization temperature)/(melting point) exceeds 0.30. The latter, of more or less empirical origin, states that amorphization should occur whenever the ionicity is ≤0.47. Stoichiometry changes are basically different from amorphization and crystallization and this is reflected in the criterion. It is shown that whether or not a substance (such as AgBr or TiO2) loses a component (such as Br or O) during bombardment correlates with the heat of atomization showing a minimum for a particular degree of loss.
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