High pressure calorimetry as applied to piezothermal analysis
作者:
Philippe Pruzan,
Le´on Ter Minassian,
Pierre Figuiere,
Henri Szwarc,
期刊:
Review of Scientific Instruments
(AIP Available online 1976)
卷期:
Volume 47,
issue 1
页码: 66-71
ISSN:0034-6748
年代: 1976
DOI:10.1063/1.1134493
出版商: AIP
数据来源: AIP
摘要:
This paper describes an apparatus which can be used to determine bulk thermal expansion coefficients of liquids as a function of temperature and pressure up to 10 kilobar in a temperature range from −20° to 100 °C. The principle of the method consists in measuring the heat of compression by a step by step procedure. The apparatus is a Joule twin calorimeter which is composed of a high pressure vessel and a reference cylinder. Temperature differences between these two components can be detected at better than 10−5K by means of a gas thermometer, thus providing high sensitivity. Results are given for liquidn‐hexane and ethyl alcohol.
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