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Thermodynamic Studies on the Complexation Reactions of Copper(II) Macrocyclic Tetramine Complexes with Monodentate Ligands: Part II. A Spectrophotometric Study on the Reactions of Meso‐5, 7, 7, 12, 14, 14‐Hexamethyl‐1, 4, 8, 11‐Tetraazacyclotetradecane‐Copper(II) (Blue) with Halide Ions

 

作者: Ming‐Chung Liou,   Kuo‐Hua Chao,   Bih‐Fong Liang,   Chung‐Sun Chung,  

 

期刊: Journal of the Chinese Chemical Society  （WILEY Available online 1978）
卷期: Volume 25, issue 1  

页码: 27-34

 

ISSN:0009-4536

 

年代: 1978

 

DOI:10.1002/jccs.197800005

 

出版商: WILEY‐VCH Verlag

 

数据来源: WILEY

 

摘要:

AbstractThe stability constants for the formation of [Cu(teta)X]+(blue) from [Cu(teta)]2+(blue) and X‐ (where X=Cl, Br, I) were determined by spectrophotometric method at 15°, 25° and 35°C. The corresponding ΔH° and ΔS° values were obtained from the variations of the stability constants between 15° and 35°C. For the same halide ion, the stability constant of [Cu(tetb)X]+(blue) is larger than that of [Cu(teta

 

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