The Fe-57 Mössbauer Effect was used to study a solution (0.2% by Weight) of 1,1′-diacetylferrocene (DAF) in the liquid crystalline materialp-n-hexyloxy-benzylidene-p-toluidine (HBT). The DAF contained enriched Fe-57. The Mössbauer Effect parameters were determined for the temperature range 100–300K in the crystalline solid phase and 100–200K in the cold smectic ß phase of HBT. Here “cold” means the smectic glass and the supercoded smectic phase. The Ln recoil-free intensity (f)vsTdata exhibited linear Debye behavior for the solid phase over the entire temperature range. The low temperature (T< 190) portion of the cold smectic InfvsTdata also exhibited Debye behavior, and the smectic glass gave a Mössbauer-Debye temperature (θlc) about 30 K. lower than the crystalline phase. The smectic glass-super cooled smectic transition was determined to beTg= 190 K from the deviation of the InfvsTdata from linear behavior. AboveTg, the deviation from linear Debye behavior followed a (T-Tg)2dependence. The smecticBglass yielded an order parameter ofS= 0.06 for DAF molecules at 100 K. Rotational and transitional diffusion were not observed for the cold smecticBphase.