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Phase transitions in perovskites with off-center ion displacements

 

作者: Yizhak Yacoby,   Yakov Girshberg,  

 

期刊: AIP Conference Proceedings  (AIP Available online 1900)
卷期: Volume 535, issue 1  

页码: 56-66

 

ISSN:0094-243X

 

年代: 1900

 

DOI:10.1063/1.1324440

 

出版商: AIP

 

数据来源: AIP

 

摘要:

We present a phenomenological model of ferroelectricity that quantitatively accounts for both displacive like and order-disorder like properties of pure perovskite ferroelectrics. We further show that this model also accounts for the dielectric and phase transition properties of incipient ferroelectrics doped with off-center impurities. Finally, we present a microscopic model that quantitatively shows that the off-center displacements in a number of perovskites is a manifestation ground state polarons. ©2000 American Institute of Physics.

 

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