Phase transitions in perovskites with off-center ion displacements
作者:
Yizhak Yacoby,
Yakov Girshberg,
期刊:
AIP Conference Proceedings
(AIP Available online 1900)
卷期:
Volume 535,
issue 1
页码: 56-66
ISSN:0094-243X
年代: 1900
DOI:10.1063/1.1324440
出版商: AIP
数据来源: AIP
摘要:
We present a phenomenological model of ferroelectricity that quantitatively accounts for both displacive like and order-disorder like properties of pure perovskite ferroelectrics. We further show that this model also accounts for the dielectric and phase transition properties of incipient ferroelectrics doped with off-center impurities. Finally, we present a microscopic model that quantitatively shows that the off-center displacements in a number of perovskites is a manifestation ground state polarons. ©2000 American Institute of Physics.
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