Epoxy systems with improved water resistance, and the non‐fickian behaviour of epoxy systems during water ageing
作者:
P. Johncock,
G. F. Tudgey,
期刊:
British Polymer Journal
(WILEY Available online 1983)
卷期:
Volume 15,
issue 1
页码: 14-18
ISSN:0007-1641
年代: 1983
DOI:10.1002/pi.4980150105
出版商: John Wiley&Sons, Ltd
数据来源: WILEY
摘要:
AbstractN,N‐Bis (2, 3‐epoxypropyl) aniline and 4,4′‐methylenebis‐[N,N‐bis (2,3‐epoxypropyl) aniline] containing bromo, chloro, trifluoromethyl or polyfluoroalkoxy substituents were synthesised and cured with aromatic diamines in order to investigate the effect of substituted halogen on water absorption. Significant improvements were achieved: thus use of 4,4′‐methylenebis‐[N, N‐bis (2, 3‐epoxypropyl)‐3, 5‐dichloroaniline] and 4,4′‐methylenebis‐[N,N‐bis (2,3‐epoxypropyl)‐3‐(trifluoromethyl) aniline] instead of 4,4′‐methylenebis‐[N,N‐bis (2,3‐epoxypropyl) aniline] reduced the water absorption by about a half. Departures from Fickian behaviour were observed during water immersion ageing at room temperature and were a general feature of the epoxy systems examined. Plots of water absorption against the Fickian parameter (√t/d) usually showed at least mild sigmoid character and were not independent of specimen thickness. Further, slow continued uptake of water occurred during long‐term ageing, and evidence is provided
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