Speeds of Sound and Isentropic Compressibilities of Alkyl Cellosolve With Aliphatic Alcohols at 308.15K
作者:
K.V. R. Reddy,
K. Rambabu,
A. Krishnaiah,
期刊:
Physics and Chemistry of Liquids
(Taylor Available online 1996)
卷期:
Volume 33,
issue 2
页码: 121-131
ISSN:0031-9104
年代: 1996
DOI:10.1080/00319109608030551
出版商: Taylor & Francis Group
关键词: Speeds of sound;2-ethoxyethanol;2-butoxyethanol;aliphatic alcohols
数据来源: Taylor
摘要:
Speeds of sound are measured in binary mixtures of alkyl cellosolve (2-ethoxyethanol and 2-butoxyethanol) with aliphatic alcohols at 308.15K. Aliphatic alcohols includes methanol, propan-1-ol, butan-1-ol, 2 methyl propan-1-ol, 2-methyl propan-2-ol and pentan-1-ol. Experimental sound speed data are used along with the density values to compute isentropic compressibilities in these mixtures. Deviations in isentropic compressibilities are negative in all the systems except in mixtures containing pentan-1-ol as non-common component, where as an inversion in sign of the function is observed. Further, speeds of sound are evaluated on the basis of Jacobson's free length theory and Schaff's collision factor theroy. The predicted values are in good agreement with the experimental results.
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