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The Ductless Siphon: A Useful Test for Evaluating Dilute Polymer Solution Elongational Behavior. Consistency with Molecular Theory and Parameters

 

作者: Keith K. K. Chao,   Michael C. Williams,  

 

期刊: Journal of Rheology  (AIP Available online 1983)
卷期: Volume 27, issue 5  

页码: 451-474

 

ISSN:0148-6055

 

年代: 1983

 

DOI:10.1122/1.549726

 

出版商: The Society of Rheology

 

数据来源: AIP

 

摘要:

The rise of an unsupported liquid column through the air from a quiescent pool to a capillary with suction (the “ductless siphon”) is interpreted approximately in terms of the elongational viscosity(η̄)of several solvents and dilute polymer solutions. The maximum height of siphon rise(h*)is used to characterize the ratioη̄/η,where η is shear viscosity, and an approximate hydrodynamic analysis showsη̄/η∼(h*)2.Measurements made for polyisobutylenes in toluene and jet fuel (kerosene), for a proprietary antimisting agent PX in jet fuel, and for polyethylene oxide and polyacrylamides in water show thath*depends on molecular variables as predicted by dilute‐solution theories forη̄/η.Polymer molecular weight range is0.8×106

 

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