The Ductless Siphon: A Useful Test for Evaluating Dilute Polymer Solution Elongational Behavior. Consistency with Molecular Theory and Parameters
作者:
Keith K. K. Chao,
Michael C. Williams,
期刊:
Journal of Rheology
(AIP Available online 1983)
卷期:
Volume 27,
issue 5
页码: 451-474
ISSN:0148-6055
年代: 1983
DOI:10.1122/1.549726
出版商: The Society of Rheology
数据来源: AIP
摘要:
The rise of an unsupported liquid column through the air from a quiescent pool to a capillary with suction (the “ductless siphon”) is interpreted approximately in terms of the elongational viscosity(η̄)of several solvents and dilute polymer solutions. The maximum height of siphon rise(h*)is used to characterize the ratioη̄/η,where η is shear viscosity, and an approximate hydrodynamic analysis showsη̄/η∼(h*)2.Measurements made for polyisobutylenes in toluene and jet fuel (kerosene), for a proprietary antimisting agent PX in jet fuel, and for polyethylene oxide and polyacrylamides in water show thath*depends on molecular variables as predicted by dilute‐solution theories forη̄/η.Polymer molecular weight range is0.8×106
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