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A Framework for the Classification of Organosulfur Transition Metal Complexes

 

作者: Lorna Linford,   HelgardG. Raubenheimer,  

 

期刊: Comments on Inorganic Chemistry  (Taylor Available online 1991)
卷期: Volume 12, issue 2-3  

页码: 113-138

 

ISSN:0260-3594

 

年代: 1991

 

DOI:10.1080/02603599108050600

 

出版商: Taylor & Francis Group

 

关键词: organosulfur compounds;sulfur-containing metal complexes

 

数据来源: Taylor

 

摘要:

More than 500 publications on the synthesis and reactivity of organosulphur transition metal complexes have appeared, but no coherent picture of the relations between the various compounds or their synthesis has emerged yet. A framework, based on simple formal conversions of thiocarbonyl and carbon disulfide complexes and the derived compound types, is now presented. The ten classes of compounds are obtained by various types of reactions of which alkylation, protonation, hydride addition, deprotonation, sulfur insertion and fragmentation are the most important.

 

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