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New “Chimie Douce” Oxidizing Processes: Electrochemical Oxidation andin situOxidation by NO2

 

作者: Jean-Claude Grenier,   Jean-Pierre Doumerc,   Yuji Muraoka,   Stephane Petit,   Michel Pouchard,   Alain Wattiaux,   Fang Zhou,  

 

期刊: Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals  (Taylor Available online 1998)
卷期: Volume 311, issue 1  

页码: 359-366

 

ISSN:1058-725X

 

年代: 1998

 

DOI:10.1080/10587259808042411

 

出版商: Taylor & Francis Group

 

关键词: electrochemical oxidation;oxygen intercalation;ammonium deintercalation;in situ nitrogen dioxide reaction

 

数据来源: Taylor

 

摘要:

Two new oxidation processes are described : the electrochemical oxidation in alkaline solution uses the electrical potential as the driving force for intercalating oxygen, at room temperature, into oxide networks such as perovskites or Ln2MO4(M ˭Ni, Cu) compounds. The second one is based on thein situdestruction of ammonium ions in oxide lattices by interaction with NO2gas, at moderate temperatures. Pictures of the reaction mechanisms are also proposed.

 

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