New “Chimie Douce” Oxidizing Processes: Electrochemical Oxidation andin situOxidation by NO2
作者:
Jean-Claude Grenier,
Jean-Pierre Doumerc,
Yuji Muraoka,
Stephane Petit,
Michel Pouchard,
Alain Wattiaux,
Fang Zhou,
期刊:
Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals
(Taylor Available online 1998)
卷期:
Volume 311,
issue 1
页码: 359-366
ISSN:1058-725X
年代: 1998
DOI:10.1080/10587259808042411
出版商: Taylor & Francis Group
关键词: electrochemical oxidation;oxygen intercalation;ammonium deintercalation;in situ nitrogen dioxide reaction
数据来源: Taylor
摘要:
Two new oxidation processes are described : the electrochemical oxidation in alkaline solution uses the electrical potential as the driving force for intercalating oxygen, at room temperature, into oxide networks such as perovskites or Ln2MO4(M ˭Ni, Cu) compounds. The second one is based on thein situdestruction of ammonium ions in oxide lattices by interaction with NO2gas, at moderate temperatures. Pictures of the reaction mechanisms are also proposed.
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