Correlation between magnetic properties and molecular structure of some metallo-mesogens
作者:
I. Bikchantaev,
Yu. Galyametdinov,
A. Prosvirin,
K. Griesar,
E.A. Soto-bustamante,
W. Haase,
期刊:
Liquid Crystals
(Taylor Available online 1995)
卷期:
Volume 18,
issue 2
页码: 231-237
ISSN:0267-8292
年代: 1995
DOI:10.1080/02678299508036618
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The behaviour of a large number of paramagnetic metallo-mesogenic molecules with Cu and VO in different mesophases in a magnetic field was investigated by EPR techniques and magnetic susceptibility measurements. The investigation of the angular dependence of the EPR spectra enabled conclusions to be reached concerning the molecular orientation in the external magnetic field. Temperature dependence magnetic susceptibility measurements were carried out in order to obtain information about the overall susceptibility anisotropy. The good agreement between experimental results and calculated data based on the known increment scheme is obvious. It is shown that the direction of orientation of the molecules in a magnetic field is predetermined by the sum of the anisotropy of the phenyl ring and the chelate core in the molecular structure.
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