首页   按字顺浏览 期刊浏览 卷期浏览 Sharkskin defects of polymer melts: The role of cohesion and adhesion
Sharkskin defects of polymer melts: The role of cohesion and adhesion

 

作者: Bernard Tremblay,  

 

期刊: Journal of Rheology  (AIP Available online 1991)
卷期: Volume 35, issue 6  

页码: 985-998

 

ISSN:0148-6055

 

年代: 1991

 

DOI:10.1122/1.550177

 

出版商: The Society of Rheology

 

关键词: Sharkskin;Adhesion;Cohesion;Melt fracture;Cavitation;MELTS;POLYMERS;ADHESION;DIES;DEFECTS;FRACTURES

 

数据来源: AIP

 

摘要:

An explanation is given for the surface defect, commonly referred to as sharkskin, considered in the present study to occur at the die exit. It will be shown numerically that large negative pressures can exist at the die exit by simulating the flow of a linear polydimethylsiloxane melt, which showed significant sharkskin, through a capillary using a finite element program. Furthermore, a series of photographs indicates that the cracks on the surface of the extrudate originate at the die exit and not further down the extrudate. It will then be postulated that negative pressure (hydrostatic tension) cavitates the polymer melt very close to the die lip (within a micron) at the die exit on the surface of the die or in the bulk of the polymer depending on the respective strengths of adhesion to the die surface at the exit or of the cohesion of the bulk of the polymer. The growth and coalescence of these voids would then lead to cracks (sharkskin) at the die exit.

 

点击下载:  PDF (628KB)



返 回